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Thermoresponsive block copolymer supported Pt nanocatalysts for base-free aerobic oxidation of 5-hydroxymethyl-2-furfural-2-furfural

《化学科学与工程前沿(英文)》 2021年 第15卷 第6期   页码 1514-1523 doi: 10.1007/s11705-021-2092-4

摘要: A base-free catalytic system for the aerobic oxidation of 5-hydroxymethyl-2-furfural was exploited by using Pt nanoparticles immobilized onto a thermoresponsive poly(acrylamide-co-acrylonitrile)-b-poly(N-vinylimidazole) block copolymer, with an upper critical solution temperature of about 45 °C. The Pt nanocatalysts were well-dispersed and highly active for the base-free oxidation of 5-hydroxymethyl-2-furfural by molecular oxygen in water, affording high yields of 2,5-furandicarboxylic acid (up to>99.9%). The imidazole groups in the block copolymer were conducive to the improvement of catalytic performance. Moreover, the catalysts could be easily separated and recovered based on their thermosensitivity by cooling the reaction system below the upper critical solution temperature. Good stability and reusability were observed over these copolymer-immobilized catalysts with no obvious decrease in catalytic activity in the five consecutive cycles.

关键词: aerobic oxidation     base-free     5-hydroxymethyl-2-furfural     Pt nanoparticle     thermoresponsive block copolymer    

Boehmite-supported CuO as a catalyst for catalytic transfer hydrogenation of 5-hydroxymethylfurfuralto 2,5-bis(hydroxymethyl)furan

《化学科学与工程前沿(英文)》 2023年 第17卷 第4期   页码 415-424 doi: 10.1007/s11705-022-2225-4

摘要: 2,5-bis(hydroxymethyl)furan (BHMF) is an important monomer of polyester. Its oxygen-containing rigid ring structure and symmetrical diol functional group establish it as an alternative to petroleum-based monomer with unique advantages for the prodution of the degradable bio-based polyester materials. Herein, we prepared a boehmite-supported copper-oxide catalyst for the selective hydrogenation of 5-hydroxymethylfurfural into BHMF via catalytic transfer hydrogenation (CTH). Further, ethanol successfully replaced conventional high-pressure hydrogen as the hydrogen donor, with up to 96.9% BHMF selectivity achieved under suitable conditions. Through characterization and factor investigations, it was noted that CuO is crucial for high BHMF selectivity. Furthermore, kinetic studies revealed a higher by-product activation energy compared to that of BHMF, which explained the influence of reaction temperature on product distribution. To establish the catalyst structure-activity correlation, a possible mechanism was proposed. The copper-oxide catalyst deactivated following CTH because ethanol reduced the CuO, which consequently decreased the active sites. Finally, calcination of the catalyst in air recovered its activity. These results will have a positive impact on hydrogenation processes in the biomass industry.

关键词: biomass     5-hydroxymethylfurfural     2     5-bis(hydroxymethyl)furan     transfer hydrogenation     catalysis    

Sodium butyrate activates HMGCS2 to promote ketone body production through SIRT5-mediated desuccinylation

《医学前沿(英文)》 2023年 第17卷 第2期   页码 339-351 doi: 10.1007/s11684-022-0943-0

摘要: Ketone bodies have beneficial metabolic activities, and the induction of plasma ketone bodies is a health promotion strategy. Dietary supplementation of sodium butyrate (SB) is an effective approach in the induction of plasma ketone bodies. However, the cellular and molecular mechanisms are unknown. In this study, SB was found to enhance the catalytic activity of 3-hydroxy-3-methylglutaryl-CoA synthase 2 (HMGCS2), a rate-limiting enzyme in ketogenesis, to promote ketone body production in hepatocytes. SB administrated by gavage or intraperitoneal injection significantly induced blood β-hydroxybutyrate (BHB) in mice. BHB production was induced in the primary hepatocytes by SB. Protein succinylation was altered by SB in the liver tissues with down-regulation in 58 proteins and up-regulation in 26 proteins in the proteomics analysis. However, the alteration was mostly observed in mitochondrial proteins with 41% down- and 65% up-regulation, respectively. Succinylation status of HMGCS2 protein was altered by a reduction at two sites (K221 and K358) without a change in the protein level. The SB effect was significantly reduced by a SIRT5 inhibitor and in Sirt5-KO mice. The data suggests that SB activated HMGCS2 through SIRT5-mediated desuccinylation for ketone body production by the liver. The effect was not associated with an elevation in NAD+/NADH ratio according to our metabolomics analysis. The data provide a novel molecular mechanism for SB activity in the induction of ketone body production.

关键词: sodium butyrate     succinylation     HMGCS2     ketogenesis     SIRT5    

Dechlorination of 2,2′,4,4′,5,5′-hexachlorobiphenyl by thermal reaction with activated carbon-supported

Yifei SUN, Xin FU, Wei QIAO, Wei WANG, Tianle ZHU, Xinghua LI

《环境科学与工程前沿(英文)》 2013年 第7卷 第6期   页码 827-832 doi: 10.1007/s11783-013-0543-y

摘要: Activated carbon (AC)-supported copper or zinc made from ion exchange resin (IRCu-C and IRZn-C) have an increased metal load of 557.3 mg?g and 502.8 mg?g compared to those prepared by the traditional method involving impregnation with AC and copper (II) citrate or zinc citrate solution (LaCu-C and LaZn-C) of 12.9 mg?g and 46.0 mg?g respectively. When applied to decompose 2,2′,4,4′,5,5′-hexachlorobiphenyl at 250 °C, IRCu-C achieved higher activity of 99.0% decomposition efficiency than LaCu-C of 84.7%, IRZn-C of 90.5% and LaZn-C of 62.7%. When the reaction temperature rose to 350 °C, all the four kinds of reactants can decompose PCB-153 with efficiency above 90%. Further, X-ray photoelectron spectroscopy characterization of IRCu-C before and after the reaction indicated transformation of 19.1% of Cu atoms into Cu , illustrating that Cu is the active ingredient or electron donor promoting the decomposition of PCB-153. The mechanism underlying this process differs from a traditional H donor. However, there is no significant change on the surface of IRZn-C before and after the reaction, suggesting that Zn acts as catalyst during the process of PCB-153 decomposition.

关键词: polychlorinated biphenyls     activated carbon-supported copper or zinc     dechlorination     electron donor    

Improvement in the synthesis of 2-(5-amino-1,2,4-thiadiazol-3-yl)-2-(Z)-methoxyiminoacetic acid 2-benzothiazolyl

GAO Shihao, SUN Chenghui, ZHAO Xinqi, GAO Changquan

《化学科学与工程前沿(英文)》 2008年 第2卷 第1期   页码 80-84 doi: 10.1007/s11705-008-0017-0

摘要: 2-(5-Amino-1,2,4-thiadiazol-3-yl)-2-(Z)-methoxyiminoacetic acid 2-benzothiazolyl thioester(III), an important intermediate of the fourth generation cephalosporins, was efficiently synthesized by reacting 2-(5-amino-1,2,4-thiadiazol-3-yl)-2-(Z)-methoxyiminoacetic acid (I) with 2,2′-dibenzothiazole disulfide (II) in the presence of triphenylphosphine. Effects of reaction time, temperature, solvents, catalysts and feeding molar ratio on the yield and quality of products were investigated, and an improved procedure suitable for industrial production was established. Using 1,2-dichloroethane as solvent, triphenylphosphine as reducer, and triethylamine as catalyst, (I) : (II) : (triphenylphosphine) = 1.0 : 1.0 : 1.0, the product was obtained at room temperature in 98.1% yield. The purity of the product without further purification is 98.7% determined by HPLC method. This procedure could be a suitable alternative to the traditional processes because of its easy handling, high yield and low cost.

关键词: 5-Amino-1     2     4-thiadiazol-3-yl     1     2-dichloroethane     important intermediate     2-benzothiazolyl thioester     temperature    

Synthesis of hydroxymethylfurfural and furfural from hardwood and softwood pulp using ferric sulphate

Agneev Mukherjee, Guillermo Portillo-Perez, Marie-Josée Dumont

《化学科学与工程前沿(英文)》 2019年 第13卷 第3期   页码 531-542 doi: 10.1007/s11705-019-1814-3

摘要: Hydroxymethylfurfural (HMF) and furfural are promising chemicals for the creation of a bio-based economy. The development of an inexpensive catalytic system for converting cellulosic biomass into these chemicals is an important step in this regard. Ferric sulphate is a common, cheap and non-toxic Lewis acid that has been used to catalyse reactions such as wood depolymerisation. In this work, ferric sulphate was used to help the production of HMF and furfural from hardwood and softwood pulps. It was found that for hardwood pulp, the use of ferric sulphate alone gave a maximum HMF yield of 31.6 mol-%. The addition of the ionic liquid [BMIM]Cl or HCl as co-catalysts did not lead to an increase in the yields obtained. A prior decationisation step, however, resulted in HMF yields of 50.4 mol-%. Softwood pulp was harder to depolymerise than hardwood, with a yield of 28.7% obtained using ferric sulphate alone. The maximum HMF yield from softwood, 37.9 mol-%, was obtained using a combination of ferric sulphate and dilute HCl. It was thus concluded that ferric sulphate is a promising catalyst for HMF synthesis from cellulosic biomass.

关键词: 5-hydroxymethylfurfural     hardwood     softwood     ferric sulphate     biorefinery    

Controlled drug release of 5-amino salicylic acid by poly(2-hydroxyethylmethacrylate) grafted agar

G. Usha RANI,Kartick Prasad DEY,Srijita BHARTI,Sumit MISHRA

《化学科学与工程前沿(英文)》 2014年 第8卷 第4期   页码 465-470 doi: 10.1007/s11705-014-1452-8

摘要: The utilization of poly (2-hydroxyethylmethacrylate) grafted agar (Ag-g-P(HEMA)) as a matrix for the controlled release of 5-aminosalicylic acid was investigated. Grafted copolymers of 2-hydroxyethylmethacrylate (HEMA) monomers on agar were synthesized by microwave assisted method. drug release studies were performed at pH values of 2 and 7 in order to investigate the possibility of pH triggered release for colon targeted drug delivery. Further, the percent grafting . (the time taken for release of 50% of the enclosed drug) value was studied and the results indicate that it may be possible to develop a programmable drug release matrix based on grafted polysaccharide. Ag-g-P(HEMA) appears to be a useful matrix for controlled release.

关键词: agar     controlled drug release     5-Amino salicylic acid     poly(2-hydroxyethylmethacrylate) grafted agar    

Endemicity of H9N2 and H5N1 avian influenza viruses in poultry in China poses a serious threat to poultry

Jiao HU,Xiufan LIU

《农业科学与工程前沿(英文)》 2016年 第3卷 第1期   页码 11-24 doi: 10.15302/J-FASE-2016092

摘要: The H9N2 and H5N1 avian influenza viruses (AIVs) have been circulating in poultry in China and become endemic since 1998 and 2004, respectively. Currently, they are prevalent in poultry throughout China. This endemicity makes them actively involved in the emergence of the novel lineages of other subtypes of influenza viruses, such as the well-known viruses of the highly pathogenic avian influenza (HPAI) H5N2 and the 2013 novel H7N7, H7N9 and H10N8 subtypes, thereby threatening both the poultry industry and public health. Here, we will review briefly the prevalence and evolution, pathogenicity, transmission, and disease control of these two subtypes and also discuss the possibility of emergence of potentially virulent and highly transmissible AIVs to humans.

关键词: avian influenza virus     H9N2     H5N1     novel viruses     public health    

UI图层合并器:基于计算机视觉与边界先验的UI图层合并方法 Research Article

陈云农1,5,甄焱鲲4,施楚宁2,李佳智2,陈柳青2,3,5,李泽健1,3,5,孙凌云2,3,5,周婷婷4,常艳芳4

《信息与电子工程前沿(英文)》 2023年 第24卷 第3期   页码 373-387 doi: 10.1631/FITEE.2200099

摘要: 随着互联网行业图形用户界面(GUI)开发工作量的快速增长,国内外学者试图从GUI图片生成可维护的前端代码。该任务更适合从包含有用户界面元数据的UI设计稿来实现代码生成。然而,碎片图层不可避免地会出现在UI设计稿中,这大大降低了生成代码的质量。目前尚未有自动化GUI技术来检测并合并碎片图层以提高生成代码的可维护性。本文提出UI图层合并器(UILM),一种基于计算机视觉的方法,可以自动检测并合并碎片图层为完整的UI组件。本文提出的UILM包含合并区域检测器和碎片图层合并算法。合并区域检测器结合边界先验知识来准确地检测出UI组件的边界。基于此,碎片图层合并算法可以搜索出边界内的相关碎片层并将其合并为整体。此外,我们提出一种动态数据增强算法来提高合并区域检测器的性能。我们还构建了用于训练合并区域检测器和测试UILM的大规模UI数据集。实验结果表明,本文提出的方法在合并区域检测方面优于最佳基线,并达到了有效的图层合并准确率。最后,对真实应用程序的用户研究也证实了本文方法的有效性。

关键词: 用户界面(UI)生成代码;UI设计规范;UI碎片图层合并;目标检测    

一种新型灰狼优化算法及其在5G频率选择表面设计中的应用 Research Article

何志豪1,2,3,晋刚1,2,3,王英俊1,2,3

《信息与电子工程前沿(英文)》 2022年 第23卷 第9期   页码 1338-1353 doi: 10.1631/FITEE.2100580

摘要: 第五代无线通信系统(5G)的发展使元启发算法与电磁设备的设计过程结合得更为紧密。本文提出一种自适应灰狼优化器(SAGWO),并将其与一种基于单元节点的5G频率选择面(FSS)优化模型相结合。在基准函数测试中,SAGWO优于其他5种优化算法:原始灰狼优化器(GWO)、遗传算法(GA)、粒子群优化器(PSO)、改进灰狼优化算法(IGWO)和基于选择性对抗的灰狼优化算法(SOGWO)。因为SAGWO具有良好全局寻优能力,所以SAGWO适用于解决具有较大设计空间的5G FSS优化问题。将SAGWO与新的FSS优化模型相结合,能自动生成在中心工作频率处具有电磁屏蔽能力的FSS结构。

关键词: 灰狼优化算法;第五代无线通信系统(5G);频率选择面;形状优化    

Correlation between serum miR-154-5p and urinary albumin excretion rates in patients with type 2 diabetes

Huiwen Ren, Can Wu, Ying Shao, Shuang Liu, Yang Zhou, Qiuyue Wang

《医学前沿(英文)》 2020年 第14卷 第5期   页码 642-650 doi: 10.1007/s11684-019-0719-3

摘要: This study aimed to investigate the correlation between serum miR-154-5p and urinary albumin to creatinine ratio (UACR) in patients with type 2 diabetes mellitus (T2DM) and the association with biomarkers of inflammation and fibrosis in diabetic kidney disease (DKD). A total of 390 patients with T2DM were divided into three groups: normal albuminuria (UACR<30 mg/g, =136, NA), microalbuminuria (UACR at 30–300 mg/g, =132, MA), and clinical albuminuria (UACR>300 mg/g, =122, CA). Circulating miR-154-5p, inflammatory (C-reactive protein (CRP); erythrocyte sedimentation rate (ESR); and tumor necrosis factor-α (TNF-α) and fibrotic markers (vascular endothelial growth factor (VEGF); transforming growth factor-β1 (TGF-β1); and fibronectin (FN)), and other biochemical indicators were assessed via real-time PCR, enzyme-linked immunosorbent assay, and chemiluminescence assay in patients with T2DM and 138 control subjects (NC). UACR, miR-154-5p, glycated hemoglobin (HbA1c), serum creatinine (sCr), blood urea nitrogen (BUN), ESR, CRP, VEGF, TNF-α, TGF-β1, and FN were significantly higher and the estimated glomerular filtration rate (eGFR) was significantly lower in NA, MA, and CA groups than in NC subjects ( <0.05). Elevated levels of UACR and miR-154-5p were directly correlated with HbA1c, sCr, BUN, ESR, CRP, VEGF, TNF-α, TGF-β1, and FN and negatively correlated with eGFR ( <0.05). miR-154-5p, HbA1c, sCr, BUN, eGFR, ESR, CRP, VEGF, TNF-α, TGF-β1, and FN were important factors affecting UACR. These findings indicated that elevated serum miR-154-5p is significantly correlated with high UACR in patients with T2DM and may offer a novel reference for the early diagnosis of DKD.

关键词: type 2 diabetes mellitus     diabetic kidney disease     miR-154-5p     urinary albumin to creatinine ratio    

Control of the agglomeration of crystals in the reactive crystallization of 5-(difluoromethoxy)-2-mercapto

Yongli WANG, Shuyuan MA, Xiaodong Lü, Chuang XIE

《化学科学与工程前沿(英文)》 2012年 第6卷 第4期   页码 423-431 doi: 10.1007/s11705-012-1211-7

摘要: 5-(Difluoromethoxy)-2-mercapto-1 -benzimidazole (DMB) was precipitated by adding acetic acid to the DMB sodium salt solution. The spherical agglomeration of DMB during the reactive crystallization in a batch crystallizer was monitored by real-time Particle Video Microscope (PVM). We found that the low feeding rate of acetic acid, high crystallization temperature, low agitation rate or adding seed crystal can facilitate the formation of spherical agglomerates. By using a simple model, the mean crystal agglomerate size of DMB thus predicted is generally in agreement with the experimental data. In addition, the crystallization process of DMB was optimized by a new control strategy of supersaturation to avoid disadvantages brought by agglomeration.

关键词: 5-(difluoromethoxy)-2-mercapto-1H-benzimidazole (DMB)     reactive crystallization     agglomeration     feeding rate     crystallization temperature     agitation rate    

Synthesis and properties of novel organogelators functionalized with 5-iodo-1,2,3-triazole and azobenzene

Ziyan Li,Yaodong Huang,Dongli Fan,Huimin Li,Shuxue Liu,Luyuan Wang

《化学科学与工程前沿(英文)》 2016年 第10卷 第4期   页码 552-561 doi: 10.1007/s11705-016-1589-8

摘要: Two series of 5-iodo-1,2,3-triazole derivatives containing azobenzene group(s) were synthesized and their gelling properties were tested. Those containing two azobenzene groups ( series) have better gelation performance than those containing one azobenzene group ( series). The microstructure of organogels and the driving force of gelation were investigated by scanning electron microscopy and H NMR, respectively. It was found that π-π stacking, van der Waals interaction, and dipole-dipole interaction were the main forces of gelation. All the tested organogels are photoresponsive and those from series are smarter than that from series. Henry - diagrams of compounds , , and were constructed on the basis of their gelation performance and the Hansen solubility parameters of related solvents. The constructed Henry - diagrams can be used to estimate the behavior of three compounds in any untested solvent.

关键词: iodo triazole     azobenzene     photoresponsive organogel     gelator-solvent effect    

Propensity score-matched study and meta-analysis of cumulative outcomes of day 2/3 versus day 5/6 embryo

null

《医学前沿(英文)》 2017年 第11卷 第4期   页码 563-569 doi: 10.1007/s11684-017-0535-6

摘要:

The superiority of the cumulative outcomes of day 5/6 embryo transfer to those of day 2/3 embryo transfer in infertile couples has been debated. This retrospective study included data collected from 1051 patients from July 2011 to June 2014. Multiple maternal baseline covariates were subjected to propensity score matching analysis, and each day 5/6 group woman was matched to one day 2/3 group woman. A systematic meta-analysis was conducted to validate the results. After matching was completed, 217 patients on the day 2/3 group were matched with those on the day 5/6 group, and no significant differences in the baseline characteristics were observed between the two groups. The cumulative pregnancy rate (57.14% vs. 53.46%, OR 1.16, 95% CI 0.79–1.70) and cumulative live birth rate (53.00% vs. 49.77%, OR 1.14, 95% CI 0.78–1.66) of day 5/6 embryo transfers were higher than those of day 2/3 embryo transfers, but this difference was not significant. The mean cycles per live birth and mean days per live birth in the day 5/6 group were significantly lower than those in the day 2/3 group. This study demonstrated that day 5/6 embryo transfer is a more cost-effective and time-efficient policy than day 2/3 embryo transfer to produce a live baby.

关键词: blastocyst     embryo transfer     cumulative pregnancy rate     cumulative live birth rate     IVF    

Responses of bacterial strains isolated from drinking water environments to N-acyl-L-homoserine lactones and their analogs during biofilm formation

Zhuoying WU, Qing WANG, Feng GUO, Shenghua ZHANG, Qipei JIANG, Xin YU

《环境科学与工程前沿(英文)》 2014年 第8卷 第2期   页码 205-214 doi: 10.1007/s11783-013-0492-5

摘要: Often as a result of biofilm formation, drinking water distribution systems (DWDS) are regularly faced with the problem of microbial contamination. Quorum sensing (QS) systems play a marked role in the regulation of microbial biofilm formation; thus, inhibition of QS systems may provide a promising approach to biofilm formation control in DWDS. In the present study, 22 bacterial strains were isolated from drinking water-related environments. The following properties of the strains were investigated: bacterial biofilm formation capacity, QS signal molecule N-acyl-L-homoserine lactones (AHLs) production ability, and responses to AHLs and AHL analogs, 3-chloro-4-(dichloromethyl)-5-hydroxy-2(5H)-furanone (MX) and 2(5H)-furanone. Four AHLs were added to developed biofilms at dosages ranging from 0.1?nmol·L to 100 nmol·L . As a result, the biofilm growth of more than 1/4 of the isolates, which included AHL producers and non-producers, were significantly promoted. Further, the biofilm biomasses were closely associated with respective AHLs concentrations. These results provided evidence to support the idea that AHLs play a definitive role in biofilm formation in many of the studied bacteria. Meanwhile, two AHLs analogs demonstrated unexpectedly minimal negative effects on biofilm formation. This suggested that, in order to find an applicable QS inhibition approach for biofilm control in DWDS, the testing and analysis of more analogs is needed.

关键词: drinking water distribution systems (DWDS)     biofilm     quorum sensing (QS)     N-acyl-L-homoserine lactones (AHLs)     (dichloromethyl)-5-hydroxy-2(5H)-furanone (MX)     2(5H)-furanone    

标题 作者 时间 类型 操作

Thermoresponsive block copolymer supported Pt nanocatalysts for base-free aerobic oxidation of 5-hydroxymethyl-2-furfural-2-furfural

期刊论文

Boehmite-supported CuO as a catalyst for catalytic transfer hydrogenation of 5-hydroxymethylfurfuralto 2,5-bis(hydroxymethyl)furan

期刊论文

Sodium butyrate activates HMGCS2 to promote ketone body production through SIRT5-mediated desuccinylation

期刊论文

Dechlorination of 2,2′,4,4′,5,5′-hexachlorobiphenyl by thermal reaction with activated carbon-supported

Yifei SUN, Xin FU, Wei QIAO, Wei WANG, Tianle ZHU, Xinghua LI

期刊论文

Improvement in the synthesis of 2-(5-amino-1,2,4-thiadiazol-3-yl)-2-(Z)-methoxyiminoacetic acid 2-benzothiazolyl

GAO Shihao, SUN Chenghui, ZHAO Xinqi, GAO Changquan

期刊论文

Synthesis of hydroxymethylfurfural and furfural from hardwood and softwood pulp using ferric sulphate

Agneev Mukherjee, Guillermo Portillo-Perez, Marie-Josée Dumont

期刊论文

Controlled drug release of 5-amino salicylic acid by poly(2-hydroxyethylmethacrylate) grafted agar

G. Usha RANI,Kartick Prasad DEY,Srijita BHARTI,Sumit MISHRA

期刊论文

Endemicity of H9N2 and H5N1 avian influenza viruses in poultry in China poses a serious threat to poultry

Jiao HU,Xiufan LIU

期刊论文

UI图层合并器:基于计算机视觉与边界先验的UI图层合并方法

陈云农1,5,甄焱鲲4,施楚宁2,李佳智2,陈柳青2,3,5,李泽健1,3,5,孙凌云2,3,5,周婷婷4,常艳芳4

期刊论文

一种新型灰狼优化算法及其在5G频率选择表面设计中的应用

何志豪1,2,3,晋刚1,2,3,王英俊1,2,3

期刊论文

Correlation between serum miR-154-5p and urinary albumin excretion rates in patients with type 2 diabetes

Huiwen Ren, Can Wu, Ying Shao, Shuang Liu, Yang Zhou, Qiuyue Wang

期刊论文

Control of the agglomeration of crystals in the reactive crystallization of 5-(difluoromethoxy)-2-mercapto

Yongli WANG, Shuyuan MA, Xiaodong Lü, Chuang XIE

期刊论文

Synthesis and properties of novel organogelators functionalized with 5-iodo-1,2,3-triazole and azobenzene

Ziyan Li,Yaodong Huang,Dongli Fan,Huimin Li,Shuxue Liu,Luyuan Wang

期刊论文

Propensity score-matched study and meta-analysis of cumulative outcomes of day 2/3 versus day 5/6 embryo

null

期刊论文

Responses of bacterial strains isolated from drinking water environments to N-acyl-L-homoserine lactones and their analogs during biofilm formation

Zhuoying WU, Qing WANG, Feng GUO, Shenghua ZHANG, Qipei JIANG, Xin YU

期刊论文